Synthesis and Reactivity of a Crystalline Zinc-cAAC Radical
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Reaction of LAmZnI [LAm = tBuC(N-DIPP)2, DIPP = 2,6-iPr2-C6H3] with KC8 in the presence of cyclic (alkyl)(amino)carbene (cAAC) affords a stable radical complex [LAmZn(cAAC)]• (3). Single-crystal structural analysis of 3 shows a short Zn─C bond and concomitan... ...
