A photoinert member of a photosensitive family. Structural studies of cobalt(III) nitropentammine malonate, [Co(NH3)5NO2]C3H2O4, under variable temperature and pressure help to explain the phenomenon
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A large family of photosensitive [Co(NH3)5NO2]XY compounds is known to manifest mechanical effects accompanying intramolecular photochemical linkage nitro-nitrito isomerization. A new member of this family, a malonate, [Co(NH3)5NO2]C3H2O4, was synthesized for ... ...
