Formation of a MnIII-O-CeIV species from a MnIII-hydroxo complex and ceric ammonium nitrate
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The addition of 1.0 equiv. ceric ammonium nitrate (CAN) to the MnIII-hydroxo complex [MnIII(OH)(PaPy2Q)]+ (1) yields a new species (2) that contains a MnIII-O-CeIV core. The MnIII oxidation state in 2 is supported by 1H NMR data, which reveal hyperfine-shifted... ...
