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Tuning the Structure and Photoluminescence of [SbCl5]2--Based Halides via Modification of Imidazolium-Based Cations

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Structure-property relationships in imidazolium-based hybrid Sb(III) chlorides provide critical guidance for designing high-performance materials. Three zero-dimensional metal halides, namely, [C3mmim]2SbCl5 (1, [C3mmim]+ = 1-propyl-2,3-dimethylimidazolium), [... ...