Radical S-adenosyl-l-methionine FeS cluster implicated as the sulfur donor during albomycin biosynthesis
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Carbon-sulfur bond-forming reactions in natural product biosynthesis largely involve Lewis acid/base chemistry with relatively few examples catalysed by radical S-adenosyl-l-methionine (SAM) enzymes. The latter have been limited to radical-mediated sulfur inse... ...
