Reactivity of Ammonia in 1,2-Addition to Group 13 Imine Analogues with G13-P-Ga Linkages: The Electronic Role of Group 13 Elements
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Using density functional theory (M06-2X-D3/def2-TZVP), we investigated the 1,2-addition reactions of NH3 with a series of heavy imine analogues, G13=P-Rea (where G13 denotes a Group 13 element; Rea = reactant), featuring a mixed G13-P-Ga backbone. Theoretical ... ...
