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FTIR Detection of Ce3+ Sites on Shape-Controlled Ceria Nanoparticles Using Adsorbed 15N2 as a Probe Molecule

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Ceria is an important redox catalyst due to the facile Ce3+/Ce4+ switching at its surface. Therefore, in situ determination of the oxidation state of surface cerium cations is of significant interest. Infrared spectroscopy of probe molecules such as CO holds g... ...