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Cooperatively Catalyzed Activation of Thioglycosides with Iodine and Iron(III) Trifluoromethanesulfonate

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Reported herein is a further expansion of the cooperatively catalyzed Koenigs-Knorr glycosylation reaction, known as "the 4K reaction". It has been discovered that molecular iodine, along with a metal salt and an acid additive, can activate thioglycosides. P... ...