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The miracle of self-assembly: a journey of the {Ln6F8} core in the world of lanthanides

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This work presents a unique example of the self-assembly of {Ln6F8} clusters composed of Ln3+ cations and F- and CF3COO- anions. The crystal structures of new fluorotrifluoroacetate compounds with the general formula A2[Ln6(μ3-F)8(tfa)12L6], where A = Na and ... ...