Mixed-valence linear CoIII2CoII complexes with easy-axis magnetic anisotropy: Experimental and theoretical investigation
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An in situ generated ligand formed by the Schiff base condensation of 3,5-di-tert-butylsalicylaldehyde and R(-) or S(+) 2-phenylglycinol was reacted with cobalt(II) acetate tetrahydrate, affording mixed-valence enantiomerically pure [CoIICoIII2(R or S-L1)2 (L2... ...