Single-Step Insertion of Organic Sulfur Into a Fe6C Carbide Carbonyl Cluster, Including the Natural Amino Acid L-Cysteine: Vibrational Circular Dichroism and Chirality Transfer
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We present a straightforward and versatile synthetic route to Fe6C carbide carbonyl clusters containing organosulfur ligands, including the chiral amino acid L- and D-cysteine. Reaction of the reduced cluster [NEt4]4[Fe6C(CO)15] (1) with thiols (RSH) or disulf... ...
