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Ligand-Controlled Chromium Catalysis for Tunable Z/E Selectivity in Asymmetric Homoallylic Alcohol Synthesis

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Chiral homoallylic alcohols with vicinal stereocenters and well-defined Z/E alkene geometries are key structural motifs in bioactive polyketides, yet their efficient and selective synthesis remains a long-standing challenge in asymmetric catalysis. Existing st... ...