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Ligand-Controlled Stereodivergent Manganese-Catalyzed Hydroalkoxylation of Alkynylnitriles to Access (E)- and (Z)-3-Alkoxyvinylnitriles

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Precise stereocontrol over functionalized alkenes remains a central challenge in organic synthesis. In particular, catalytic methods enabling flexible and stereodivergent synthesis of both trans-selective and cis-selective useful enol ethers are still underdev... ...