首页 正文

Smiles-Truce Cascades Enable Heteroaryl Cyclopropane and Sultine Synthesis

{{output}}
We describe a triple C─C bond cascade process for heteroaryl cyclopropane synthesis, through the reaction of vinyl sulfonium salts and sulfones under mild conditions. An initial conjugate addition (C─C bond 1) sets up a Smiles-Truce rearrangement (C─C bond ... ...