Belt-Sulfur Mobilization as a Crucial Mechanistic Feature Shared between the Vanadium and Molybdenum Nitrogenases
{{output}}
Nitrogenase catalyzes the reduction of N2 to NH3 at its active-site cofactor. Recent studies of the 'conventional' Mo-nitrogenase suggest a plausible involvement of all cofactor belt-S sites in catalysis. Here, we use analytical, enzymatic and spectroscopic ... ...
