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Tautomerism and switching in 7-hydroxy-8-(azophenyl)quinoline and similar compounds

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Tautomerism in two new azo dyes, based on 7-hydroxyquinoline, has been considered from the viewpoint of the proton crane concept. Although 8-(phenyldiazenyl)quinolin-7-ol exists in solution as a mixture of azo and two hydrazone tautomers, as shown by the exper... ...