Surface Protected Organozirconium Catalyzes C-H Alumination of Saturated Hydrocarbons
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Surface grafted organozirconium-catalyzes C-H/Et-Al exchange reactions, involving saturated hydrocarbons and AlEt3, to afford organoaluminum compounds and ethane. The Zr(OtBu)3@SiO2-Al2O3-700 (1) catalyst contains monopodal ≡SiO-Zr(OtBu)3 and only a few resid... ...
