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Ag⁺-Mediated Structural Reconstruction of a Metastable Cu35 Cluster Toward Cu-Ag Heterometallic Architectures for Superior Electrocatalytic CO2-to-Ethanol Conversion

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Controlled structural transformations of metal nanoclusters (NCs) via dynamic bond reorganization provide fundamental insights into cluster reactivity and open avenues for functionality tuning. Here, we report a thiacalix[4]arene-protected Cu(I)-alkynide clust... ...