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Isochalcogenourea-catalyzed asymmetric (4 + 2)-heterocycloadditions of allenoates

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Allenoates are versatile reagents that can be used for numerous (formal) cycloaddition reactions under (chiral) Lewis base catalysis. Most commonly, the catalysts of choice are phosphines, amines, and N-heterocyclic carbenes. We have recently established the u... ...