ACS applied materials & interfaces. 2025 Jun 13. doi: 10.1021/acsami.5c06881 Q18.22025

Achieving Improved Buried Interface Enabled by Oriented Bridging Molecules in Near-Infrared Perovskite Light-Emitting Diodes

取向桥接分子实现高性能近红外钙钛矿发光二极管中的优异界面性能翻译改进

Xin-Yuan Gao¹, Xin-Ye Wu², Wei-Jia Wang³, Jin-Zhe Xu¹, Wei-Zhi Liu¹, Shuai-Hao Xu¹, Zhi-Yun Peng³, Dong-Ying Zhou¹, Liang-Sheng Liao^{1 4}

作者单位 +展开

作者单位

¹ Institute of Functional Nano and Soft Materials (FUNSOM), Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou, Jiangsu 215123, China.

² College of Nano Science and Technology (CNST), Soochow University, Suzhou, Jiangsu 215123, China.

³ Soochow Institute for Energy and Materials Innovations (SIEMIS), College of Energy, Soochow University, Suzhou, Jiangsu 215006, China.

⁴ Macao Institute of Materials Science and Engineering, Macau University of Science and Technology, Taipa 999078, Macau, China.

DOI: 10.1021/acsami.5c06881 PMID: 40512592

摘要中英对照阅读

Metal halide perovskites exhibit great promise for applications in solid-state lighting and flat-panel display technologies. Despite significant progress, the current strategies for achieving high-performance perovskite light-emitting diodes (PeLEDs) are largely confined to additive engineering and upper interface modifications, with little attention paid to the buried interface, which plays a crucial role in perovskite crystal growth and charge transport.... ...点击完成人机验证后继续浏览

金属卤化物钙钛矿在固态照明和平板显示技术领域展现出巨大的应用前景。尽管已经取得了显著的进展，但目前实现高性能钙钛矿发光二极管（PeLEDs）的主要策略仍然主要集中在添加剂工程和上层界面修改方面，而对埋藏界面的关注较少，埋藏界面对于钙钛矿晶体生长和电荷传输起着至关重要的作用。在这里，我们展示了一种新颖的埋藏界面修饰策略，通过将聚乙二醇化聚乙烯亚胺（PEIE）替换为磷酸乙醇胺（PEA）。PEA作为ZnO与钙钛矿之间的桥接分子，其磷酸基团锚定在ZnO上，氨基则充当钙钛矿成核位点并钝化钙钛矿缺陷。此外，PEA还能钝化ZnO的表面缺陷，并调节其能级，从而增强电子注入。由此制备的PeLEDs表现出高达22.3%的峰值EQE，效率滚降减小且半衰期延长，在798 nm的峰值波长下优于传统的PeLEDs。

关键词：缺陷钝化；界面修饰；钙钛矿；磷酸乙醇胺；自组装单分子层。

翻译效果不满意？用Ai改进或寻求AI助手帮助，对摘要进行重点提炼

相关内容

期刊名：Acs applied materials & interfaces

缩写：ACS APPL MATER INTER

ISSN：1944-8244

e-ISSN：1944-8252

IF/分区：8.2/Q1

文章目录更多期刊信息

全文链接

官方链接

PMC全文

引文链接

复制

已复制！

格式：

Achieving Improved Buried Interface Enabled by Oriented Bridging Molecules in Near-Infrared Perovskite Light-Emitting Diodes

取向桥接分子实现高性能近红外钙钛矿发光二极管中的优异界面性能翻译改进

Flipped polyelectrolyte multilayer films: accessing the buried interface

倒置的聚电解质多层膜：访问埋藏界面

Tailored Polymer Hole-Transporting Materials with Multisite Passivation Functions for Effective Buried-Interface Engineering of Inverted Quasi-2D Perovskite Solar Cells

用于倒置准二维钙钛矿太阳能电池有效埋藏界面工程的多点位钝化功能聚合物空穴传输材料

Synchronous Perovskite Crystallization Regulation and Buried Interface Modification Improve the Stability and Efficiency of a Planar Inorganic Perovskite Solar Cell

同步钙钛矿结晶调控和埋藏界面修饰提升平面无机钙钛矿太阳能电池的稳定性及效率

Minimizing Buried Interface Energy Losses with Post-Assembled Chelating Molecular Bridges for High-Performance and Stable Inverted Perovskite Solar Cells

利用后组装的螯合分子桥减少埋底界面能量损耗，实现高性能和稳定的倒置钙钛矿太阳能电池

Enhancing Charge Collection of Tin-Based Perovskite Solar Cells by Optimizing the Buried Interface with a Multifunctional Self-Assembled Monolayer

通过多功能自组装单层优化埋藏界面以提高锡基钙钛矿太阳能电池的电荷收集效率

Buried Ni/Cu(001) interface at the atomic scale

原子尺度下埋藏的Ni/Cu(001)界面

Layerwise reaction at a buried interface

埋藏界面的逐层反应

Dual Buried Interface Engineering for Improving Air-Processed Inverted FAPbI3 Perovskite Solar Cells

双埋界面工程提高空气处理的倒置FAPbI3钙钛矿太阳能电池性能

Achieving Improved Buried Interface Enabled by Oriented Bridging Molecules in Near-Infrared Perovskite Light-Emitting Diodes

取向桥接分子实现高性能近红外钙钛矿发光二极管中的优异界面性能 翻译改进

Flipped polyelectrolyte multilayer films: accessing the buried interface

倒置的聚电解质多层膜：访问埋藏界面

Tailored Polymer Hole-Transporting Materials with Multisite Passivation Functions for Effective Buried-Interface Engineering of Inverted Quasi-2D Perovskite Solar Cells

用于倒置准二维钙钛矿太阳能电池有效埋藏界面工程的多点位钝化功能聚合物空穴传输材料

Synchronous Perovskite Crystallization Regulation and Buried Interface Modification Improve the Stability and Efficiency of a Planar Inorganic Perovskite Solar Cell

同步钙钛矿结晶调控和埋藏界面修饰提升平面无机钙钛矿太阳能电池的稳定性及效率

Minimizing Buried Interface Energy Losses with Post-Assembled Chelating Molecular Bridges for High-Performance and Stable Inverted Perovskite Solar Cells

利用后组装的螯合分子桥减少埋底界面能量损耗，实现高性能和稳定的倒置钙钛矿太阳能电池

Enhancing Charge Collection of Tin-Based Perovskite Solar Cells by Optimizing the Buried Interface with a Multifunctional Self-Assembled Monolayer

通过多功能自组装单层优化埋藏界面以提高锡基钙钛矿太阳能电池的电荷收集效率

Buried Ni/Cu(001) interface at the atomic scale

原子尺度下埋藏的Ni/Cu(001)界面

Layerwise reaction at a buried interface

埋藏界面的逐层反应

Dual Buried Interface Engineering for Improving Air-Processed Inverted FAPbI3 Perovskite Solar Cells

双埋界面工程提高空气处理的倒置FAPbI3钙钛矿太阳能电池性能

取向桥接分子实现高性能近红外钙钛矿发光二极管中的优异界面性能翻译改进