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Synthesis of Indolyl-7-azanorbornanes by Decomposition of Tetrahydro-1,2,3-triazepines

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We report a new method for the synthesis of indolyl-7-azanobornanes. The process involves the generation of a meta-stable tetrahydro-1,2,3-triazepine intermediate that decomposes by extrusion of molecular nitrogen and ultimately leads to the formation of the o... ...