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Accommodating Styrenes and Unactivated Olefins: Hydrotrifluoromethylation Using O, O'-Dimethyldithiophosphoric Acid as SET Reductant and H Atom Donor

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Styrenes are challenging substrates for current trifluoromethyl radical-involved hydrotrifluoromethylation reactions due to competitive side reactions. Moreover, metal-free hydrotrifluoromethylation of olefins that can simultaneously be compatible with styrene... ...