On the Unexpected Formation of [2.2.1]- and [2.1.1]Homotriblattanes
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A new class of polycyclic caged compounds, the [2.n.1]homotriblattanes, is described herein. These scaffolds are accessed through a concise, three-step sequence featuring an unexpected radical cyclization of α-bromocyclopropyl ketones. Their structures and st... ...
