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Divergent Organomagnesium Reactivity of Rigid, Dinucleating Naphthyridine Ligands: Backbone Changes with Big Impact

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We report the synthesis and characterization of two naphthyridine-based ligands bearing pendant secondary amine and amide donors, respectively. We additionally report their deprotonation chemistry and reactivity with dialkylmagnesium and Grignard reagents. The... ...