The Impact of Ligand Oxidation State and Fold Angle on the Charge Transfer Processes of MoIVO-Dithione Complexes
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We report a series of mononuclear monooxo Mo(IV) complexes possessing either one or two fully oxidized dithiolene ligands; [MoOCl(R2Dt0)2][X], (1 and 2), and MoO(p-SC6H4Y)2(R2Dt0), (3 and 4), (R=Me, i Pr; X= PF6, SbF6, BF4; Y= H, Cl, F, CF3, Me, t Bu, OMe). Ei... ...
