Magneto-Structural Characterization of Heterometallic NiII2MnII2/NiII2CoII2 Cubane Complexes with a Compartmental Ligand
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We report a combined experimental and theoretical magneto-structural study of four heterometallic isostructural complexes: [Ni2Mn2(L)2(OAc)2{N(CN)2}]·5H2O (1), [Ni2Mn2(L)2(OAc)2(N3)2]·MeCN (2), [Ni2Mn2(L)2(OAc)2(NCS)2]·H2O (3), and [Ni2Co2(L)2(OAc)2(NCS)2]... ...