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Cs4Ca[Si8O19]: a new mixed tetrahedral-octahedral oxosilicate, its topological features and comparison with other interrupted framework silicates

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Single crystals of a previously unknown caesium calcium silicate with the composition Ca4Ca[Si8O19] have been obtained during a systematic study of the phase relations and compound formation in the system Cs2O-CaO-SiO2. Structure determination was based on a s... ...