Flash Communication: Pd2Zn2 Clusters from the Reduction of Palladium(II) Dichloride Precursors with Metallic Zinc
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We report the synthesis and solid-state characterization of two unusual Pd2Zn2 clusters formed from the partial reduction of [PdL2Cl2] precursors (L2 = dcpe or dppe) with metallic zinc. The new clusters have been characterized by single crystal X-ray diffracti... ...