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Synthesis of triple-decker sandwich compounds featuring a M-M bond through cyclo-Bi5 and cyclo-Sb5 rings

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The cyclopentadienyl anion is a π-aromatic five-membered ring ligand that is widely used in organometallic chemistry. By replacing the CH groups in cyclopentadiene with isoelectronic group-15 elements, an inorganic analogue can be obtained. In this line, Pn5 ... ...