Catalyst Activation and Speciation Involving DyadPalladate Precatalysts in Suzuki-Miyaura and Buchwald-Hartwig Cross-Couplings
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Understanding mechanisms underpinning Pd precatalyst activation and formation of active species is important in maximizing catalyst activity and lifetime. DyadPalladate precatalysts, represented by the general formula [R3PH+]2[Pd2Cl6]2- (R3P = tertiary alkylph... ...
