首页 正文

Soft matter. 2025 Jan 10. doi: 10.1039/d4sm01213e Q22.82025

Stabilizing bicontinuous particle-stabilized emulsions formed via solvent transfer-induced phase separation

溶剂转移诱导相分离形成的双连续粒子稳定乳液的稳定性研究 翻译改进

Meyer T Alting  1, Martin F Haase  1

作者单位 +展开

作者单位

  • 1 Van 't Hoff Laboratory of Physical and Colloid Chemistry, Department of Chemistry, Debye Institute for Nanomaterials Science, Utrecht University, Utrecht, The Netherlands. m.f.haase@uu.nl.
  • DOI: 10.1039/d4sm01213e PMID: 39792080

    摘要 Ai翻译

    Bicontinuous particle-stabilized emulsions (bijels) are unique soft materials that combine the bulk properties of two immiscible fluids into a single interconnected structure. This structure is achieved through the formation of two interwoven fluid networks, stabilized by an interfacial layer of colloidal particles. Bijels with submicron-scale domain networks can be synthesized via solvent transfer-induced phase separation (STrIPS). However, the fluid network structure in STrIPS-bijels tends to degrade over time, limiting their practical applications. In this study, we identify that the destabilization of STrIPS-bijels is driven by the exchange of matter between the bijel and the surrounding oil phase. Confocal laser scanning microscopy reveals that over time, aqueous components from the bijel dissolve into the surrounding oil, leading to an inward flow of oil into the bijel. This process disrupts the fluid bicontinuous structure within hours. To extend the stability of the bijel to several weeks, we explore strategies to reduce the dissolution of the aqueous phase and the inflow of oil. Specifically, we investigate the effects of the oil's chemical composition and properties, as well as modifications to the surface chemistry of the supporting glass substrates. Our results show that while the particle scaffold of STrIPS-bijels exhibits long-term stability, the maintenance of the fluid bicontinuous network depends on minimizing the loss of aqueous components. The enhanced control over the stability of the fluid bicontinuous structure developed in this work is critical for advancing STrIPS-bijels as functional materials for applications in catalysis, separations, and energy storage.

    Copyright © Soft matter. 中文内容为AI机器翻译,仅供参考!

    期刊名:Soft matter

    缩写:SOFT MATTER

    ISSN:1744-683X

    e-ISSN:1744-6848

    IF/分区:2.8/Q2

    文章目录 更多期刊信息

    全文链接
    引文链接
    复制
    已复制!
    推荐内容
    Stabilizing bicontinuous particle-stabilized emulsions formed via solvent transfer-induced phase separation