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Expanding the Chemistry of Pentafluorophenyl-N-Confused Porphyrin: Diketonate Substitution and Derivatizations at the External 3-C Position of the Inverted Pyrrole Ring

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In this study, we synthesized two new 3-C-substituted pentafluorophenyl-N-confused porphyrins (PFNCPs), one with acetylacetonate (PFNCP-acac, 2a) and the other with ylidene-2-propanone (PFNCP-ac, 3a), through a one-pot reaction in the absence of a catalyst. Un... ...