Molecular basis for the diversification of lincosamide biosynthesis by pyridoxal phosphate-dependent enzymes
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The biosynthesis of the lincosamide antibiotics lincomycin A and celesticetin involves the pyridoxal-5'-phosphate (PLP)-dependent enzymes LmbF and CcbF, which are responsible for bifurcation of the biosynthetic pathways. Despite recognizing the same S-glycosyl... ...
