A [Mn8] Defective Supertetrahedron T3 and Its Dimeric [Mn16] Analogue
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The initial use of 2-(pyridin-2-yl)propane-1,3-diol (pypdH2) in Mn cluster chemistry has afforded two new mixed-valence polynuclear Mn clusters, namely, [Mn8Ο5(pypd)(hmp)3(O2CCMe3)8] (1) and [Mn16Ο10(N3)2(pypd)2{(py)2CO2}4(O2CEt)12] (2) (hmp- = deprotonated ... ...
