Flash Communication: Rhodium Complexes of Acetamide-Derived PAlP Pincer
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The new alane/bis(phosphine) PAlP pincer-type ligands 2-Me and 2-Et have been prepared by protolysis reactions of N-(diisopropylphoshino)acetamide with Me3Al or Et3Al in a 2:1 ratio. Upon reaction with a "RhCl" source and pyridine, 2-Me gave rise to a (PAlP)Rh... ...
