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Rhodium-Catalyzed Arene Alkenylation: Selectivity and Reaction Mechanism as a Function of In Situ Oxidant Identity

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Rhodium catalyzed arene alkenylation reactions with arenes and olefins using dioxygen as the direct oxidant (e.g., ACS Catal. 2020, 10, 11519), Cu(II) carboxylates (e.g., Science 2015, 348, 421; J. Am. Chem. Soc. 2017, 139, 5474) or Fe(III) carboxylate cluster... ...