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Rh → Sb Interactions Supported by Tris(8-quinolyl)antimony Ligands

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The ligands tris(8-quinolyl)stibine and tris(6-methyl-8-quinolyl)stibine have been synthesized and complexed to rhodium using (MeCN)3RhCl3. The resulting complexes feature an unusual [RhSb]VI core as a result of the formal insertion of the antimony center into... ...