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Synthesis of Quinoline-Based Pt-Sb Complexes with L- or Z-Type Interaction: Ligand-Controlled Redox via Anion Transfer

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A series of Pt-Sb complexes with two or three L-type quinoline side arms were prepared and studied. Two ligands, tri(8-quinolinyl)stibane (SbQ3, Q = 8-quinolinyl, 1) and 8,8'-(phenylstibanediyl)diquinoline (SbQ2Ph, 2), were used to synthesize the PtII-SbIII co... ...