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Synthesis and Structure-Property Relationship of meso-Substituted Porphyrin- and Benzoporphyrin-Thiophene Conjugates toward Electrochemical Reduction of Carbon Dioxide

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A novel series of ZnII-trans-A2B2 porphyrins and benzoporphyrins bearing phenyl and thiophene-based meso-substituents was successfully synthesized and characterized by spectroscopic and electrochemical techniques. Systematic comparison among the compounds in t... ...