Synthesis and Reactivity of Dipalladated Derivatives of Terephthalaldehyde
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The polynuclear complex [{μ-C1,C4,N,N″-C6H2{C(H)=N(nBu)}2-2,5}{Pd(μ-OAc)}]2 (I) reacts with tbbpy (4,4'-di-tert-butyl-2,2'-bipyridine) and TlOTf to form the dinuclear complex [{μ-C1,C4,N,N″-C6H2{C(H)=N(nBu)}2-2,5}{Pd(tbbpy)}2] (1). The hydrolysis of I wit... ...
