A Unified Model for Non-Fickian Diffusion and Anomalous Swelling of Glassy Polymer Gels
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A sheet of glassy polymers placed in a solvent shows swelling behaviors quite different from that of soft polymers (rubbers and gels). (1) Non-Fickian diffusion (called case II diffusion): As solvent permeates into the sample, a sharp front is created between ... ...