Synthesis and Characterization of Palladium Pincer Bis(carbene) CCC Complexes
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The metalation of the DIPPCCC (DIPPCCC = bis(diisopropylphenyl-imidazol-2-ylidene)phenyl) ligand platform with Pd was achieved under mild conditions by reacting [H3(DIPPCCC)]Cl2 with Pd(OAc)2 at room temperature in the presence of 3.1 equiv of LiN(SiMe3)2. The... ...
