Synthesis and crystal structure of diiso-thio-cyanato-tetra-kis-(4-methyl-pyridine N-oxide)cobalt(II) and diiso-thio-cyanato-tris-(4-methyl-pyridine N-oxide)cobalt(II) showing two different metal coordination polyhedra
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The reaction of Co(NCS)2 with 4-methyl-pyridine N-oxide (C6H7NO) leads to the formation of two compounds, namely, tetra-kis-(4-methyl-pyridine N-oxide-κO)bis-(thio-cyanato-κN)cobalt(II), [Co(NCS)2(C6H7NO)4] (1), and tris-(4-methyl-pyridine N-oxide-κO)bis-(t... ...
