An octa-nuclear nickel(II) pyrazolate cluster with a cubic Ni8 core and its methyl- and n-octyl-functionalized derivatives
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The mol-ecular and crystal structure of a discrete [Ni8(μ4-OH)6(μ-4-Rpz)12]2- (R = H; pz = pyrazolate anion, C3H3N2 -) cluster with an unprecedented, perfectly cubic arrangement of its eight Ni centers is reported, along with its lower-symmetry alkyl-functio... ...
