Synthesis, crystal structure and properties of chlorido-tetra-kis-(pyridine-3-carbo-nitrile)-thio-cyanato-iron(II)
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Reaction of FeCl2·4H2O with KSCN and 3-cyano-pyridine (pyridine-3-carbo-nitrile) in ethanol accidentally leads to the formation of single crystals of Fe(NCS)(Cl)(3-cyano-pyridine)4 or [FeCl(NCS)(C6H4N2)4]. The asymmetric unit of this compound consists of one ... ...