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New Mode of Asymmetric Induction for Enantioselective Radical N-Heterobicyclization via Kinetically Stable Chiral Radical Center

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Enantioselective radical N-heterobicyclization of N-allylsulfamoyl azides have been developed via metalloradical catalysis (MRC). The Co(II)-based catalytic system can homolytically activate the organic azides with varied electronic and steric properties for a... ...