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Desulfurization and N2 Binding at an Iron Complex Derived from the C-S Activation of Benzothiophene

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Metal insertion into the C-S bonds of thiophenes is a facile route to interesting polydentate ligand scaffolds with C and S donors. Here, we describe iron-mediated C-S activation of a diphenylphosphine-functionalized benzothiophene proligand. Metalation of the... ...