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Room-Temperature Columnar Liquid Crystals from Twisted and Macrocyclic 9,9'-Bifluorenylidene Mesogen with Ambipolar Carrier Transport Properties

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We herein report the synthesis and characterization of a series of twisted and conjugated 9,9'-bifluorenylidene (BF) derivatives and a ladder-shaped cyclic dimer (CBF) bearing eight long alkoxy chains at peripheral positions. These contorted aromatics formed h... ...