Crystal structure of (μ-hydrogen di-sulfato)-μ-oxido-bis-[(4,4'-di- tert-butyl-2,2'-bi-pyridine)-oxidovanadium(IV/V)] aceto-nitrile monosolvate
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The dinuclear oxidovanadium(IV/V) complex, [V2(HS2O8)O3(C18H24N2)2]·CH3CN or [V2O2(μ-O)(μ-H(SO4)2)(4,4'-tBubpy)2]·CH3CN (4,4'-tBubpy = 4,4'-di-tert-butyl-2,2'-bi-pyridine), has crystallographic C 2 symmetry and exhibits a distorted octa-hedral geometry aro... ...
