Crystal structure of Cs2GdNb6Cl15O3 in the structural evolution of niobium oxychlorides with octa-hedral Nb6-cluster units
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Cs2GdNb6Cl15O3, dicaesium gadolinium hexa-niobium penta-deca-chloride trioxide, was synthesized by solid-state reactions starting from a stoichiometric mixture of CsCl, Gd2O3, Nb, NbCl5, and Nb2O5. The crystal structure is based on octa-hedral Nb6 cluster unit... ...
